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Battery Breakthrough?
A Texas company says it can make a new ultracapacitor power system to
replace the electrochemical batteries in everything from cars to
laptops.
A secretive Texas startup developing what
some are calling a "game changing" energy-storage technology broke its
silence this week. It announced that it has reached two production
milestones and is on track to ship systems this year for use in electric
vehicles.
EEStor's ambitious goal, according to patent documents, is to "replace
the electrochemical battery" in almost every application, from
hybrid-electric and pure-electric vehicles to laptop computers to
utility-scale electricity storage.
The company boldly claims that its system, a kind of battery-ultracapacitor
hybrid based on barium-titanate powders, will dramatically outperform
the best lithium-ion batteries on the market in terms of energy density,
price, charge time, and safety. Pound for pound, it will also pack 10
times the punch of lead-acid batteries at half the cost and without the
need for toxic materials or chemicals, according to the company.
The implications are enormous and, for many, unbelievable. Such a
breakthrough has the potential to radically transform a transportation
sector already flirting with an electric renaissance, improve the
performance of intermittent energy sources such as wind and sun, and
increase the efficiency and stability of power grids--all while
fulfilling an oil-addicted America's quest for energy security.
The breakthrough could also pose a threat to next-generation lithium-ion
makers such as Watertown, MA-based A123Systems, which is working on a
plug-in hybrid storage system for General Motors, and Reno, NV-based
Altair Nanotechnologies, a supplier to all-electric vehicle maker
Phoenix Motorcars.
"I get a little skeptical when somebody thinks they've got a silver
bullet for every application, because that's just not consistent with
reality," says Andrew Burke, an expert on energy systems for
transportation at University of California at Davis.
That said, Burke hopes to be proved wrong. "If [the] technology turns
out to be better than I think, that doesn't make me sad: it makes me
happy."
Richard Weir, EEStor's cofounder and chief executive, says he would
prefer to keep a low profile and let the results of his company's
innovation speak for themselves. "We're well on our way to doing
everything we said," Weir told Technology Review in a rare interview. He
has also worked as an electrical engineer at computing giant IBM and at
Michigan-based automotive-systems leader TRW.
Much like capacitors, ultracapacitors store energy in an electrical
field between two closely spaced conductors, or plates. When voltage is
applied, an electric charge builds up on each plate.
Ultracapacitors have many advantages over traditional electrochemical
batteries. Unlike batteries, "ultracaps" can completely absorb and
release a charge at high rates and in a virtually endless cycle with
little degradation.
Where they're weak, however, is with energy storage. Compared with
lithium-ion batteries, high-end ultracapacitors on the market today
store 25 times less energy per pound.
This is why ultracapacitors, with their ability to release quick jolts
of electricity and to absorb this energy just as fast, are ideal today
as a complement to batteries or fuel cells in electric-drive vehicles.
The power burst that ultracaps provide can assist with stop-start
acceleration, and the energy is more efficiently recaptured through
regenerative braking--an area in which ultracap maker Maxwell
Technologies has seen significant results.
On the other hand, EEStor's
system--called an Electrical Energy Storage Unit, or EESU--is based on
an ultracapacitor architecture that appears to escape the traditional
limitations of such devices. The company has developed a ceramic
ultracapacitor with a barium-titanate dielectric, or insulator, that can
achieve an exceptionally high specific energy--that is, the amount of
energy in a given unit of mass.
For example, the company's system claims a specific energy of about 280
watt hours per kilogram, compared with around 120 watt hours per
kilogram for lithium-ion and 32 watt hours per kilogram for lead-acid
gel batteries. This leads to new possibilities for electric vehicles and
other applications, including for the military.
"It's really tuned to the electronics we attach to it," explains Weir.
"We can go all the way down from pacemakers to locomotives and
direct-energy weapons."
The trick is to modify the composition of the barium-titanate powders to
allow for a thousandfold increase in ultracapacitor voltage--in the
range of 1,200 to 3,500 volts, and possibly much higher.
EEStor claims that, using an automated production line and existing
power electronics, it will initially build a 15-kilowatt-hour
energy-storage system for a small electric car weighing less than 100
pounds, and with a 200-mile driving range. The vehicle, the company
says, will be able to recharge in less than 10 minutes.
The company announced this week that this year it plans to begin
shipping such a product to Toronto-based ZENN Motor, a maker of
low-speed electric vehicles that has an exclusive license to use the
EESU for small- and medium-size electric vehicles.
By some estimates, it would only require $9 worth of electricity for an
EESU-powered vehicle to travel 500 miles, versus $60 worth of gasoline
for a combustion-engine car.
"My understanding is that the leap from powder to product isn't the big
leap," says Ian Clifford, CEO of ZENN, which is also an early investor
in EEStor. "We're the first application, and that's thrilling for us. We
took the initial risk because we believed in what they are doing. And
energy storage is the game changer."
The key challenge, however, is to ensure that the barium-titanate
powders can be made on a production line without compromising purity and
stability. "Purification gives you better production stability, gives
you better permittivity, and gives you the high voltages you're looking
for," says Weir. "We've now got the chemicals certified and purified to
the point we're looking for." (Better permittivity of the insulator
improves the amount of charge that can be stored without letting the
current leak across the two plates.)
EEStor announced this week that the first automated production line for
its powder has performed as required and that permittivity will meet or
exceed expectations. It also said that it achieved 99.9994 percent
purity for its barium-nitrate powder, a crucial ingredient in the
dialectric. San Antonia-based Southwest Research Institute independently
confirmed the results.
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